ABSTRACT

Dendrimers are molecules with very special properties due to their

symmetric hyperbranched structure based on the connection of self-

similar chemical groups. The term “dendrimer” is derived from the

Greekwords dendros, whichmeans “tree,” andmeros, meaning “part” (Crampton and Simanek, 2007). In fact, the structure of a dendrimer

resembles that of a tree crown. Somehow, dendrimers may be

considered as a peculiar variant of polymers where the monomers

systematically branch off, generating a tree-like structure, instead

of simply connecting linearly to each other forming a single, long

flexible-chain characteristic of ordinary polymers. However, con-

trary to common synthetic polymers, which have significant levels

of polydispersity (heterogeneity of molecular weights), dendrimers

are, in general, practically monodisperse (i.e., a sample is composed

of similar molecules). This important property is related to the

particular sequential synthetic procedures used in the preparation

of dendrimers.