ABSTRACT

Catalytic cracking is different to thermal cracking insofar as a catalyst is used for the catalytic process. The mechanism of catalytic cracking is also different insofar as the mechanism of the thermal process involves free radical intermediates whereas the mechanism of the catalytic process involves ionic intermediates (Table 9.1). However, there has been the claim that, in some cases, the feedstock constituents decompose by thermolysis before the species may come into contact with the catalyst.