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      Chapter

      Thermodynamics and Kinetics of Corrosion Processes
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      Chapter

      Thermodynamics and Kinetics of Corrosion Processes

      DOI link for Thermodynamics and Kinetics of Corrosion Processes

      Thermodynamics and Kinetics of Corrosion Processes book

      Thermodynamics and Kinetics of Corrosion Processes

      DOI link for Thermodynamics and Kinetics of Corrosion Processes

      Thermodynamics and Kinetics of Corrosion Processes book

      ByDavid E.J. Talbot, James D.R. Talbot
      BookCorrosion Science and Technology

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      Edition 3rd Edition
      First Published 2018
      Imprint CRC Press
      Pages 80
      eBook ISBN 9781351259910
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      ABSTRACT

      Thermodynamics provides part of the scientific infrastructure needed to evaluate the course and rate of corrosion processes. Its principle value is in yielding information on intermediate products of the complementary anodic and cathodic partial reactions that together constitute a complete process. The chapter discusses thermodynamics of aqueous corrosion which includes oxidation and reduction processes in aqueous solution and oxidation states, and presents kinetics of aqueous corrosion. In the long term, the degradation of engineering metals and alloys by corrosion is inevitable and so resistance to it is essentially concerned with the rates of corrosion. The polarization characteristics for an electrode refer to the relation between current and applied potential, including activation, concentration and resistance contributions. The chapter provides information on thermodynamics and kinetics of dry oxidation, oxidation of metals forming cation interstitial oxides, cation vacancy oxides and anion vacancy oxides.

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