ABSTRACT

Acknowledgments .............................................................................................................. 580

References .......................................................................................................................... 580

The discovery of efficient electroluminescence in thin films of conjugated polymers in 1990

initiated a large international effort by academics, industries, and national laboratories to

understand and develop a new technology based on polymer light emitters. From the scientific

point of view, such a large effort opened new avenue for research in the area of charge transport

in disordered, highly correlated, and low-dimension materials, as well as in the novel synthesis

of semiconducting polymers and small-molecule organics with unprecedented purity. From the

technology point of view, such materials promised a complete paradigm shift in the manufac-

ture of semiconducting devices, enabling inexpensive liquid-based processing under atmos-

pheric conditions rather than expensive high-temperature and vacuum-based processing. This

promise motivated significant progress in polymer material development, purity, and stability,

and helped to revitalize the promise for two other related fields, namely organic photovoltaics

and transistors. Organic-based light-emitting devices are now competitive to many inorganic-

based devices in efficiency and stability. Nonetheless, the initial promise of inexpensive liquid-

based or print-based manufacturing has yet to be fully realized.