ABSTRACT

Polysulfides were first discovered and patented in about 1927 by J.C. Patrick by accident in attempting to develop antifreeze. The polymer was called Thiokol A, a condensation reaction of ethylene dichloride and sodium tetrasulfide, for which manufacturing began in 1929 [1]. This elastomer was quite difficult to process due to its variability and thermoplastic nature, leading to the discontinuation of manufacture after improved grades were developed.