ABSTRACT
Water Solubility (g/m3 or mg/L at 25°C or as indicated and reported temperature dependence equations. Additional data at other temperatures designated * are compiled at the end of this section): 5.94 (shake flask-UV, Andrews & Keefer 1949) 7.48* (shake flask-UV, measured range 0.4-42.8°C, Bohon & Claussen 1951) 3.87 (shake flask-UV, Sahyun 1966) 7.08* (shake flask-UV, measured range 0-64.5°C, Wauchope & Getzen 1972) R·ln x = –4520/(T/K) + 4.08 × 10-4·[(T/K) – 298.15]2 – 20.8 + 0.0273·(T/K), temp range 24.6-73.4°C (shake
flask-UV measurements, Wauchope & Getzen 1972) 7.45 (shake flask-GC, Eganhouse & Calder 1976) 7.0 (shake flask-fluorescence, Mackay & Shiu 1977) 8.50 (shake flask-nephelometry, Hollifield 1979) 7.51 (shake flask-LSC, Banerjee et al. 1980) 8.09 (TLC-RT correlation, Bruggeman et al. 1982) 6.71 (generator column-GC/ECD, Miller et al. 1984, 1985; quoted, Hawker 1989b) 7.09 (recommended, Pearlman et al. 1984) 7.05 (vapor saturation-UV, Akiyoshi et al. 1987) 6.5 (29°C, shake flask-GC/FID; Stucki & Alexander 1987) 7.20, 7.55 (generator column-HPLC/UV, Billington et al. 1988)
7.2* (recommended, IUPAC Solubility Data Series, Shaw 1989) log [SL/(mol/L)] = 1.872 –973.4/(T/K) (supercooled liquid, Passivirta et al. 1999) ln x = –1.5792 – 3669.26/(T/K), temp range 5-50°C (regression eq. of literature data, Shiu & Ma 2000) 5.37, 5.32 (generator column-GC/ECD, different flow rates, Oleszek-Kudlak et al. 2004)
Vapor Pressure (Pa at 25°C or as indicated and reported temperature dependence equations. Additional data at other temperatures designated * are compiled at the end of this section): 7933* (162.5°C, isoteniscope-manometer, measured range 162.5-255.2°C, Chipman & Peltier 1929) 104* (69.20°C, temp range 69.20-271.2°C, Cunningham 1930; quoted, Boublik et al. 1984) 133.3* (70.6°C, summary of literature data, temp range 70.6-254.0°C, Stull 1947) 1.30 (effusion method, measured range 4.0-34.5°C, Bright 1951) log (P/mmHg) = 10.38 – 3799/(T/K); temp range: 4.0-34.5°C (Antoine eq., effusion, Bright 1951) 0.031 (manometry, Augood et al. 1953; selected, Bidleman 1984) 1.273* (effusion method, measured range 15.05-40.55°C, Bradley & Cleasby 1953) log (P/cmHg) = 11.282 – 4263/(T/K); temp range 15.05-40.55°C (Antoine eq., Bradley & Cleasby 1953) log (P/mmHg) = [ – 0.2185 × 12910.0/(T/K)] + 8.218583; temp range 70.6-254.9°C (Antoine eq., Weast
1972-73) 1.41* (effusion method, interpolated-Antoine eq., measured range 24.9-50.33°C, Radchenko & Kitiagor-
odskii 1974) log (P/mmHg) = 12.6789 – 4367.436/(T/K); temp range; 24.9-50.33°C (Antoine eq., Knudsen effusion, Rad-
chenko & Kitiagorodskii 1974) 2040* (123.0°C, pressure transducer, measured range 123.0-327.55°C, Nasir et al. 1980) 1.40 (HPLC-RT correlation, Swann et al. 1983) log (P/atm) = [1 – 528.437/(T/K)] × 10^{0.821410 – 2.73337 × 10-4·(T/K) + 1.02285 × 10-7·(T/K)2}; temp
range: 342.35-673.15 K (Cox eq., Chao et al. 1983) 3.35, 3.41 (PGC by GC-RT correlation, different GC columns, Bidleman 1984) 5.608 (supercooled liquid PL, converted from literature PS with ∆Sfus Bidleman 1984) log (P/kPa) = 6.36895 – 1997.558/(202.608 + t/°C), temp range: 69.2-271.1°C (Antoine eq. from reported exptl.
