ABSTRACT

The majority of phase transformations that occur in the solid state take place by thermally activated atomic movements. The transformations that will be dealt with in this chapter are those that are induced by a change of temperature of an alloy that has a xed bulk composition. Usually we will be concerned with the transformations caused by a temperature change from a single-phase region of a (binary) phase diagram to a region where one or more other phases are stable. The different types of phase transformations that are possible can be roughly divided into the following groups: (a) precipitation reactions, (b) eutectoid transformations, (c) ordering reactions, (d) massive transformations, and (e) polymorphic changes. Figure 5.1 shows several different types of binary phase diagrams that are representative of these transformations.