ABSTRACT

Decomposition..................................................................... 393 5.2 Decomposed in Domains of Equilibrium Composition. . 395

6 External F ields............................................................................... 396 6.1 Pressure................................................................................. 397 6.2 S hear...................................................................................... 401

7 Polymer Blends with Additives of a Good Solvent and a Diblock Copolym er................................................................... 403 7.1 Low Molecular Weight Solvents......................................... 403 7.2 Addition of a Diblock C opolym er.................................... 404

8 Summary........................................................................................ 408

Appendix................................................................................................ 409

Acknowledgements............................................................................... 409

Glossary of Sym bols.......................................................................... 409

References............................................................................................. 410

1 Introduction

During the last decades there has both in academia and in industry been lots of attention to the phase behaviour of polymer blends. Industrial applica­ tions tend to use still more complex polymeric systems, where the miscibility parameters play an essential role. 1 There is therefore a broad economic interest on the exploration of basic thermodynamic equilibrium properties as well as gain of better understanding on the non-equilibrium behaviour.