ABSTRACT

The word polymer literally means “many parts.” A polymer is a macromo­ lecule that contains many groups of atoms, called monomeric units, that are covalently bonded. The simplest hydrocarbon chain polymer is polyethy­ lene, with the general formula:

$, iC H 2-CH23r $2

obtained from the monomer ethylene, H2C = CH2. The number of ethylene monomeric units, n , can reach values between

103 and 106. For high molecular weight chains, terminal groups <\>x and cj)2 are present in low concentrations and will therefore have no effect on the

mechanical properties of the polymer. Terminal groups influence mainly the chemical stability of the polymer. Heating or irradiation can provoke the degradation of polymers with unstable terminal groups.