ABSTRACT

Detection Limits for Various Electrochemical Techniques ........................................................... 325 Values of (2.3026 RT/F) at Different Temperatures ...................................................................... 326 Potential of Zero Charge (Eecm) for Various Electrode Materials in Aqueous

Solutions at Room Temperature ........................................................................................... 327 Variation of Reference Electrode Potentials with Temperature .................................................... 328 pH Values of Standard Solutions Used in the Calibration of Glass Electrodes ............................. 329 Temperature Versus pH Correlation of Standard Solutions Used for the Calibration of

Electrodes ...........................................................................................................................330 Solid Membrane Electrodes ........................................................................................................... 331 Liquid Membrane Electrodes......................................................................................................... 332 Standard Reduction Electrode Potentials for Inorganic Systems in Aqueous

Solutions at 25 °C .......................................................................................................333 Standard Reduction Electrode Potentials for Inorganic Systems in Nonaqueous

Solution at 25 °C .................................................................................................................336 Redox Potentials for Some Biological Half-Reactions .................................................................. 337 Standard EMF of the Cell H2/HCl/AgCl, Ag in Various Aqueous Solutions of Organic

Solvents at Different Temperatures ...................................................................................... 338 Temperature Dependence of the Standard Potential of the Silver Chloride Electrode ................. 339 Standard Electrode Potentials of Electrodes of the First Kind ......................................................340 Standard Electrode Potentials of Electrodes of the Second Kind ................................................. 341 Polarographic Half-Wave Potentials (E½) of Inorganic Cations .................................................... 342 Polarographic E½ Ranges (in V vs. SCE) for the Reduction of Benzene Derivatives ................... 345 Vapor Pressure of Mercury ............................................................................................................346 Organic Functional Group Analysis of Nonpolarographic Active Groups ................................... 347 Coulometric Titrations ................................................................................................................... 349

The following table provides guidance in selection of electrochemical techniques by providing the relative sensitivities of various methods [1]. The limit of detection of lead, defined as the minimum detectable quantity (on a mole basis), is used as the basis of comparison.