ABSTRACT
Polymer (B): poly(tert-butyl acrylate-b-methyl methacrylate) 2008AYD Characterization: Mn/g.mol1 = 69000, Mw/g.mol1 = 80700, 5 mol% tert-BA ________________________________________________________________________
Solvent (A) T-range/ MHA/ solHA(vap)/ K kJ/mol kJ/mol _______________________________________________________________________________
chlorobenzene 423.15-443.15 −1.7 −36.4 n-decane 423.15-443.15 23.4 −18.4 ethyl acetate 423.15-443.15 5.9 −21.8 ethylbenzene 423.15-443.15 10.0 −25.5 isopropylbenzene 423.15-443.15 17.2 −19.7 3-methylbutyl acetate 423.15-443.15 7.95 −31.4 n-nonane 423.15-443.15 26.4 −11.3 n-octane 423.15-443.15 21.3 −12.1 propyl acetate 423.15-443.15 7.1 −24.3 propylbenzene 423.15-443.15 6.7 −31.8 toluene 423.15-443.15 3.8 −27.6 _______________________________________________________________________________ Polymer (B): poly(tert-butyl acrylate-b-methyl methacrylate) 2006SAK Characterization: Mn/g.mol1 = 69000 (9000-b-60000), 5 mol% tert-BA ________________________________________________________________________
Solvent (A) T-range/ MHA/ solHA(vap)/ K kJ/mol kJ/mol _______________________________________________________________________________
benzene 413.15-443.15 5.4 −22.2 butyl acetate 413.15-443.15 9.2 −26.0 tert-butyl acetate 413.15-443.15 8.4 −32.7 chlorobenzene 413.15-443.15 −1.7 −36.4 ethyl acetate 413.15-443.15 5.9 −21.8 ethylbenzene 413.15-443.15 10.0 −25.5 isopropylbenzene 413.15-443.15 17.2 −19.7 isobutyl acetate 413.15-443.15 11.3 −21.8 3-methylbutyl acetate 413.15-443.15 7.95 −31.4 propyl acetate 413.15-443.15 7.1 −24.3 2-propyl acetate 413.15-443.15 1.3 −28.1 propylbenzene 413.15-443.15 6.7 −31.8 toluene 413.15-443.15 3.8 −27.6 _______________________________________________________________________________
________________________________________________________________________ Polymer (B): poly(tert-butyl acrylate-b-methyl methacrylate) 2008AYD Characterization: Mn/g.mol1 = 62000, Mw/g.mol1 = 45000, 16 mol% tert-BA ________________________________________________________________________
Solvent (A) T-range/ MHA/ solHA(vap)/ K kJ/mol kJ/mol _______________________________________________________________________________
chlorobenzene 418.15-443.15 12.1 −22.2 n-decane 418.15-443.15 36.8 −4.6 ethyl acetate 418.15-443.15 9.62 −18.0 ethylbenzene 418.15-443.15 23.0 −12.5 isopropylbenzene 418.15-443.15 34.3 −27.6 3-methylbutyl acetate 418.15-443.15 30.5 −8.8 n-nonane 418.15-443.15 31.8 −5.4 n-octane 418.15-443.15 29.3 −4.2 propyl acetate 418.15-443.15 12.1 −19.2 propylbenzene 418.15-443.15 23.4 −15.1 toluene 418.15-443.15 19.2 −12.6 _______________________________________________________________________________ Polymer (B): poly(3,4-dichlorobenzyl methacrylate-co-ethyl methacrylate) 2001DEM Characterization: 13 mol% ethyl methacrylate, synthesized in the laboratory ________________________________________________________________________
Solvent (A) T-range/ MHA/ K kJ/mol _______________________________________________________________________________
methanol 403.15-423.15 22.86 ethanol 403.15-423.15 54.04 2-propanone 403.15-423.15 20.09 2-butanone 403.15-423.15 18.01 methyl acetate 403.15-423.15 18.71 ethyl acetate 403.15-423.15 20.79 benzene 403.15-423.15 19.40 toluene 403.15-423.15 14.90 1,2-dimethylbenzene 403.15-423.15 13.10 n-octane 403.15-423.15 27.71 n-nonane 403.15-423.15 29.10 n-decane 403.15-423.15 16.63 n-undecane 403.15-423.15 27.02 n-dodecane 403.15-423.15 21.48 _______________________________________________________________________________
________________________________________________________________________ Polymer (B): poly(3,4-dichlorobenzyl methacrylate-co-ethyl methacrylate) 2001KA1 Characterization: 27 mol% ethyl methacrylate, Tg/K = 336.2, (298 K) = 1.09 g/cm3, synthesized in the laboratory ________________________________________________________________________
Solvent (A) T-range/ MHA/ K kJ/mol _______________________________________________________________________________
methanol 403.15-423.15 24.94 ethanol 403.15-423.15 61.66 2-propanone 403.15-423.15 18.71 2-butanone 403.15-423.15 19.40 methyl acetate 403.15-423.15 20.09 ethyl acetate 403.15-423.15 22.86 benzene 403.15-423.15 19.40 toluene 403.15-423.15 22.17 1,2-dimethylbenzene 403.15-423.15 21.48 n-octane 403.15-423.15 31.87 n-nonane 403.15-423.15 28.41 n-decane 403.15-423.15 11.09 n-dodecane 403.15-423.15 21.48 _______________________________________________________________________________ Polymer (B): poly(3,4-dichlorobenzyl methacrylate-co-ethyl methacrylate) 2001KA1 Characterization: 60 mol% ethyl methacrylate, Tg/K = 334.2, (298 K) = 1.14 g/cm3, synthesized in the laboratory ________________________________________________________________________
Solvent (A) T-range/ MHA/ K kJ/mol _______________________________________________________________________________
methanol 403.15-423.15 22.17 ethanol 403.15-423.15 65.82 2-propanone 403.15-423.15 19.70 2-butanone 403.15-423.15 21.48 methyl acetate 403.15-423.15 19.40 ethyl acetate 403.15-423.15 22.86 benzene 403.15-423.15 22.17 toluene 403.15-423.15 23.56 1,2-dimethylbenzene 403.15-423.15 20.09 n-octane 403.15-423.15 25.64 n-nonane 403.15-423.15 29.79 n-decane 403.15-423.15 31.87 n-dodecane 403.15-423.15 26.33 _______________________________________________________________________________
________________________________________________________________________ Polymer (B): poly(3,4-dichlorobenzyl methacrylate-co-ethyl methacrylate) 2001KA1 Characterization: 70 mol% ethyl methacrylate, Tg/K = 332.2, (298 K) = 1.14 g/cm3, synthesized in the laboratory ________________________________________________________________________
Solvent (A) T-range/ MHA/ K kJ/mol _______________________________________________________________________________
methanol 403.15-423.15 27.71 ethanol 403.15-423.15 67.21 2-propanone 403.15-423.15 16.63 2-butanone 403.15-423.15 18.71 methyl acetate 403.15-423.15 20.09 ethyl acetate 403.15-423.15 20.09 benzene 403.15-423.15 21.48 toluene 403.15-423.15 23.56 1,2-dimethylbenzene 403.15-423.15 18.71 n-octane 403.15-423.15 27.02 n-nonane 403.15-423.15 28.41 n-decane 403.15-423.15 29.79 n-dodecane 403.15-423.15 24.25 _______________________________________________________________________________ Polymer (B): poly(3,4-dichlorobenzyl methacrylate-co-ethyl methacrylate) 2001KA1 Characterization: 82 mol% ethyl methacrylate, Tg/K = 331.2, (298 K) = 1.17 g/cm3, synthesized in the laboratory ________________________________________________________________________
Solvent (A) T-range/ MHA/ K kJ/mol _______________________________________________________________________________
methanol 403.15-423.15 29.79 ethanol 403.15-423.15 65.82 2-propanone 403.15-423.15 35.34 2-butanone 403.15-423.15 17.32 methyl acetate 403.15-423.15 22.86 ethyl acetate 403.15-423.15 18.01 benzene 403.15-423.15 22.17 toluene 403.15-423.15 14.55 1,2-dimethylbenzene 403.15-423.15 13.86 n-octane 403.15-423.15 27.71 n-nonane 403.15-423.15 31.18 n-decane 403.15-423.15 27.02 n-dodecane 403.15-423.15 9.70 _______________________________________________________________________________
________________________________________________________________________ Polymer (B): poly(3,4-dichlorobenzyl methacrylate-co-ethyl methacrylate) 2001DEM Characterization: 93 mol% ethyl methacrylate, synthesized in the laboratory ________________________________________________________________________
Solvent (A) T-range/ MHA/ K kJ/mol _______________________________________________________________________________
methanol 403.15-423.15 28.41 ethanol 403.15-423.15 73.44 2-propanone 403.15-423.15 27.71 2-butanone 403.15-423.15 23.56 methyl acetate 403.15-423.15 29.79 ethyl acetate 403.15-423.15 21.48 benzene 403.15-423.15 24.94 toluene 403.15-423.15 14.55 1,2-dimethylbenzene 403.15-423.15 18.71 n-octane 403.15-423.15 29.79 n-nonane 403.15-423.15 32.56 n-decane 403.15-423.15 33.26 n-undecane 403.15-423.15 13.86 n-dodecane 403.15-423.15 7.62 _______________________________________________________________________________ Polymer (B): poly[2-(N,N-dimethylamino)ethyl methacrylate]-b-2-(N-morpholino)ethyl methacrylate] 2008YAZ Characterization: Mn/g.mol1 = 33500, Mw/g.mol1 = 38200, 50 mol%/50 mol%, Tg/K = 332.5, (298 K) = 1.0892 g/cm3, synthesized in the laboratory ________________________________________________________________________
Solvent (A) T-range/ MHA/ K kJ/mol _______________________________________________________________________________
n-hexane 383.15-413.15 8.55 n-heptane 383.15-413.15 10.9 n-octane 383.15-413.15 7.21 n-nonane 383.15-413.15 3.30 n-decane 383.15-413.15 3.39 cyclopentane 383.15-413.15 7.23 cyclohexane 383.15-413.15 5.31 cycloheptane 383.15-413.15 1.19 benzene 383.15-413.15 −2.32 toluene 383.15-413.15 −1.28 _______________________________________________________________________________
________________________________________________________________________ Polymer (B): poly[dimethylsiloxane-co-methyl (4-cyanobiphenoxy)butylsiloxane] 2002PRI Characterization: 50 mol% dimethylsiloxane, 40 repeat units, Merck, Ltd., UK _______________________________________________________________________________
Solvent (A) T/ solHA/ K kJ/mol _______________________________________________________________________________
n-pentane 358.15 −14.9 n-hexane 358.15 −19.9 n-heptane 358.15 −22.5 n-octane 358.15 −25.3 n-nonane 358.15 −29.6 2-methylhexane 358.15 −17.8 3-methylhexane 358.15 −19.4 2,3-dimethylpentane 358.15 −20.2 2,4-dimethylpentane 358.15 −18.3 2,2,3-trimethylbutane 358.15 −17.6 cyclohexane 358.15 −29.0 benzene 358.15 −25.3 toluene 358.15 −28.5 ethylbenzene 358.15 −30.2 1,2-dimethylbenzene 358.15 −32.2 1,3-dimethylbenzene 358.15 −31.8 1,4-dimethylbenzene 358.15 −31.5 _______________________________________________________________________________ Polymer (B): poly(glycidyl methacrylate-co-butyl methacrylate) 2002KAY Characterization: Mn/g.mol1 = 530000, Mw/g.mol1 = 738000, 41 mol% butyl methacrylate, Tg/K = 334, = 1.178 g/cm3 _______________________________________________________________________________
Solvent (A) T-range/ MHA/ K kJ/mol _______________________________________________________________________________
n-pentane 403.15-423.15 3.93 n-hexane 403.15-423.15 5.56 n-heptane 403.15-423.15 6.90 n-octane 403.15-423.15 8.07 n-nonane 403.15-423.15 9.61 n-decane 403.15-423.15 10.7 benzene 403.15-423.15 5.85 toluene 403.15-423.15 6.19 1,4-dimethylbenzene 403.15-423.15 7.73 tetrachloromethane 403.15-423.15 0.63 1-chloropropane 403.15-423.15 3.05 1-chlorobutane 403.15-423.15 3.68 _______________________________________________________________________________
________________________________________________________________________ Polymer (B): poly(glycidyl methacrylate-co-ethyl methacrylate) 2002KAY Characterization: Mn/g.mol1 = 441000, Mw/g.mol1 = 700000, 44 mol% ethyl methacrylate, Tg/K = 355, = 1.186 g/cm3 ________________________________________________________________________
Solvent (A) T-range/ MHA/ K kJ/mol _______________________________________________________________________________
n-pentane 403.15-423.15 3.47 n-hexane 403.15-423.15 4.89 n-heptane 403.15-423.15 4.89 n-octane 403.15-423.15 7.73 n-nonane 403.15-423.15 9.20 n-decane 403.15-423.15 9.99 benzene 403.15-423.15 5.52 toluene 403.15-423.15 5.48 1,4-dimethylbenzene 403.15-423.15 6.98 tetrachloromethane 403.15-423.15 1.05 1-chloropropane 403.15-423.15 2.84 1-chlorobutane 403.15-423.15 4.39 _______________________________________________________________________________ Polymer (B): poly(glycidyl methacrylate-co-methyl methacrylate) 2002KAY Characterization: Mn/g.mol1 = 555000, Mw/g.mol1 = 710000, 38 mol% methyl methacrylate, Tg/K = 373, = 1.204 g/cm3 ________________________________________________________________________
Solvent (A) T-range/ MHA/ K kJ/mol _______________________________________________________________________________
n-pentane 403.15-423.15 3.76 n-hexane 403.15-423.15 5.10 n-heptane 403.15-423.15 6.40 n-octane 403.15-423.15 7.90 n-nonane 403.15-423.15 9.28 n-decane 403.15-423.15 10.4 benzene 403.15-423.15 5.23 toluene 403.15-423.15 5.60 1,4-dimethylbenzene 403.15-423.15 7.23 1,4-dioxane 403.15-423.15 4.10 tetrachloromethane 403.15-423.15 0.59 1-chloropropane 403.15-423.15 2.63 1-chlorobutane 403.15-423.15 2.63 _______________________________________________________________________________
________________________________________________________________________ Polymer (B): poly(3-mesityl-2-hydroxypropyl methacrylate-co-1-vinyl-2-pyrrolidinone) 2005ACI Characterization: Mn/g.mol1 = 58000, Mw/g.mol1 = 481000, 45.75 mol% 1-vinyl-2-pyrrolidinone, Tg/K = 380, (298 K) = 1.040 g/cm3, synthesized in the laboratory ________________________________________________________________________
Solvent (A) T-range/ MHA/ solHA(vap)/ K kJ/mol kJ/mol _______________________________________________________________________________
n-hexane 373.15-413.15 −12.35 n-hexane 413.15-453.15 29.18 n-heptane 373.15-413.15 −12.35 n-heptane 413.15-453.15 30.23 n-octane 373.15-413.15 −8.42 n-octane 413.15-453.15 33.88 n-decane 373.15-413.15 −19.91 n-decane 413.15-453.15 43.25 methanol 373.15-413.15 −9.13 methanol 413.15-453.15 31.86 ethanol 373.15-413.15 −11.76 ethanol 413.15-453.15 37.26 1-propanol 373.15-413.15 −10.76 1-propanol 413.15-453.15 40.15 1-butanol 373.15-413.15 −9.04 1-butanol 413.15-453.15 44.17 1-pentanol 373.15-413.15 −12.02 1-pentanol 413.15-453.15 44.42 _______________________________________________________________________________ Polymer (B): poly(methylhydrosiloxane-co-dimethylsiloxane) 2007COS Characterization: HMS-013 ________________________________________________________________________
Solvent (A) T-range/ MHA/ solHA(vap)/ K kJ/mol kJ/mol _______________________________________________________________________________
methyl acetate 313.15-353.15 6.7 −23.9 ethyl acetate 313.15-353.15 5.0 −28.5 tert-butyl acetate 313.15-353.15 4.1 −33.1 n-pentane 313.15-353.15 1.5 −23.9 n-hexane 313.15-353.15 0.33 −29.7 n-heptane 313.15-353.15 0.46 −33.9 _______________________________________________________________________________
________________________________________________________________________ Polymer (B): poly[(2-phenyl-1,3-dioxolane-4-yl)methyl methacrylate-co-butyl methacrylate] 2003ACI Characterization: Mn/g.mol1 = 301100, Mw/g.mol1 = 880200, 55.0 mol% butyl methacrylate, Tg/K = 370, (298 K) = 1.217 g/cm3, could be a block copolymer, synthesized in the laboratory ________________________________________________________________________
Solvent (A) T-range/ MHA/ K kJ/mol _______________________________________________________________________________
1-butanol 413.15-453.15 31.06 ethanol 413.15-453.15 29.68 methanol 413.15-453.15 26.79 1-pentanol 413.15-453.15 28.80 1-propanol 413.15-453.15 31.98 _______________________________________________________________________________ Polymer (B): poly[(2-phenyl-1,3-dioxolane-4-yl)methyl methacrylate-co-ethyl methacrylate] 2009KAR Characterization: Mn/g.mol1 = 365400, Mw/g.mol1 = 1215000, 52 mol% ethyl methacrylate, (298 K) = 1.21 g/cm3, Tg/K = 363, synthesized in the laboratory ________________________________________________________________________
Solvent (A) T-range/ solHA(vap)/ K kJ/mol _______________________________________________________________________________
1-butanol 393.15-433.15 −13.86 ethanol 393.15-433.15 −15.13 n-heptane 393.15-433.15 −11.33 n-hexane 393.15-433.15 −11.05 n-octane 393.15-433.15 −16.61 1-propanol 393.15-433.15 −15.16 _______________________________________________________________________________
________________________________________________________________________ Polymer (B): poly[(2-phenyl-1,3-dioxolane-4-yl)methyl methacrylate-co-glycidyl methacrylate] 2004ILT Characterization: Mn/g.mol1 = 244000, Mw/g.mol1 = 623400, 60.0 mol% glycidyl methacrylate, Tg/K = 367, (298 K) = 1.229 g/cm3, could be a block copolymer, synthesized in the laboratory ________________________________________________________________________
Solvent (A) T-range/ MHA/ K kJ/mol _______________________________________________________________________________
ethanol 413.15-463.15 24.27 1-propanol 413.15-463.15 26.64 1-butanol 413.15-463.15 28.44 1-pentanol 413.15-463.15 25.16 n-hexane 413.15-463.15 15.79 n-heptane 413.15-463.15 20.37 n-octane 413.15-463.15 22.40 n-decane 413.15-463.15 28.10 _______________________________________________________________________________ Polymer (B): poly[(2-phenyl-1,3-dioxolane-4-yl)methyl methacrylate-co-styrene] 2006KAR Characterization: Mn/g.mol1 = 181000, Mw/g.mol1 = 436500, unknown styrene content, Tg/K = 373-383, synthesized in the laboratory ________________________________________________________________________
Solvent (A) T-range/ solHA(vap)/ K kJ/mol _______________________________________________________________________________
ethanol 393.15-423.15 −5.9 1-propanol 393.15-423.15 −6.8 1-butanol 393.15-423.15 −13.5 n-hexane 393.15-423.15 −4.2 n-heptane 393.15-423.15 −3.7 n-octane 393.15-423.15 −4.1 _______________________________________________________________________________
________________________________________________________________________ Polymer (B): poly[2-(3-phenyl-3-methylcyclobutyl)-2-hydroxyethyl methacrylate-co-methacrylic acid] 2001KA2 Characterization: Mn/g.mol1 = 17200, Mw/g.mol1 = 45000, 45 mol% methacrylic acid, synthesized in the laboratory ________________________________________________________________________
Solvent (A) T-range/ MHA/ K kJ/mol _______________________________________________________________________________
methanol 423.15-453.15 26.63 ethanol 423.15-453.15 29.73 2-propanone 423.15-453.15 24.95 2-butanone 423.15-453.15 27.42 methyl acetate 423.15-453.15 10.47 ethyl acetate 423.15-453.15 15.16 benzene 423.15-453.15 12.64 toluene 423.15-453.15 15.83 1,2-dimethylbenzene 423.15-453.15 14.82 n-dodecane 423.15-453.15 18.30 _______________________________________________________________________________ Polymer (B): poly[styrene-b-(1-butene-co-ethylene)-b-styrene] 2009OVE Characterization: Mη/g.mol1 = 90000, 32 wt% styren, REPSOL-YPF, Madrid, Spain ________________________________________________________________________
Solvent (A) T-range/ MHA/ solHA(vap)/ K kJ/mol kJ/mol _______________________________________________________________________________
benzene 303.15-333.15 −0.7 −35.4 cyclohexane 303.15-333.15 −0.5 −33.8 cyclopentane 303.15-333.15 −5.0 −33.0 1,2-dimethylbenzene 303.15-333.15 −2.0 −43.5 ethylbenzene 303.15-333.15 −1.4 −41.7 n-heptane 303.15-333.15 −3.0 −38.4 n-hexane 303.15-333.15 −2.3 −32.8 1-hexene 303.15-333.15 −3.4 −35.2 methylcyclohexane 303.15-333.15 −1.3 −36.0 n-octane 303.15-333.15 −2.6 −42.8 n-pentane 303.15-333.15 −6.8 −32.8 tetrahydrofuran 303.15-333.15 −2.5 −35.6 toluene 303.15-333.15 −0.4 −39.0 _______________________________________________________________________________
________________________________________________________________________ Polymer (B): poly(styrene-b-ethylene oxide-b-styrene) 2007ZOU Characterization: Mn/g.mol1 = 11900, Mw/g.mol1 = 16700, 42 wt% ethylene oxide, Tm/K = 328.3 _______________________________________________________________________________
Solvent (A) T-range/ MHA/ solHA(vap)/ K kJ/mol kJ/mol _______________________________________________________________________________
n-hexane 343.15-393.15 20.13 −7.72 n-heptane 343.15-393.15 19.31 −13.26 n-octane 343.15-393.15 18.49 −18.96 n-nonane 343.15-393.15 17.28 −24.52 n-decane 343.15-393.15 16.43 −29.77 methyl acetate 343.15-393.15 8.44 −20.63 ethyl acetate 343.15-393.15 7.90 −23.89 propyl acetate 343.15-393.15 6.90 −28.46 butyl acetate 343.15-393.15 6.34 −32.83 pentyl acetate 343.15-393.15 6.80 −37.14 methanol 343.15-393.15 9.13 −26.60 ethanol 343.15-393.15 10.98 −28.08 1-propanol 343.15-393.15 9.91 −32.86 1-butanol 343.15-393.15 8.69 −37.65 1-pentanol 343.15-393.15 7.21 −41.96 _______________________________________________________________________________ Polymer (B): poly(styrene-b-ethylene oxide-b-styrene) 2007ZOU Characterization: Mn/g.mol1 = 11200, Mw/g.mol1 = 14300, 60 wt% ethylene oxide, Tm/K = 335 _______________________________________________________________________________
Solvent (A) T-range/ MHA/ solHA(vap)/ K kJ/mol kJ/mol _______________________________________________________________________________
n-hexane 343.15-393.15 17.83 −10.03 n-heptane 343.15-393.15 17.02 −15.56 n-octane 343.15-393.15 15.98 −21.48 n-nonane 343.15-393.15 14.86 −26.94 n-decane 343.15-393.15 14.24 −31.97 methyl acetate 343.15-393.15 7.47 −21.61 ethyl acetate 343.15-393.15 6.76 −25.04 propyl acetate 343.15-393.15 5.91 −29.46 butyl acetate 343.15-393.15 5.24 −33.93 pentyl acetate 343.15-393.15 5.73 −38.21 methanol 343.15-393.15 12.36 −23.37 ethanol 343.15-393.15 11.88 −27.19 1-propanol 343.15-393.15 10.11 −32.66 1-butanol 343.15-393.15 9.20 −37.13 1-pentanol 343.15-393.15 7.95 −41.21 _______________________________________________________________________________
________________________________________________________________________ Polymer (B): poly(styrene-g-ethyl methacrylate) 2006TEM Characterization: 68 units EMA/graft, 54% of styrene-units are grafted, Tg/K = 358, synthesized in the laboratory ________________________________________________________________________
Solvent (A) T-range/ MHA/ K kJ/mol _______________________________________________________________________________
1-butanol 413.15-463.15 30.73 n-decane 413.15-463.15 30.02 ethanol 413.15-463.15 28.64 n-heptane 413.15-463.15 20.45 n-hexane 413.15-463.15 18.25 methanol 413.15-463.15 24.95 n-nonane 413.15-463.15 27.85 n-octane 413.15-463.15 23.82 1-pentanol 413.15-463.15 30.94 1-propanol 413.15-463.15 28.26 tetrachloromethane 413.15-463.15 15.95 _______________________________________________________________________________ Polymer (B): poly[tetrafluoroethylene-co-perfluoro(methyl vinyl ether)] 2007FOS Characterization: 5 mol% perfluoro(methyl vinyl ether), Tm/K = 549, = 2.121 g/cm3, 35wt% crystallinity, Hyflon, Solvay Solexis
Comments: From sorption data not from IGC. ________________________________________________________________________
Solvent (A) T-range/ MHA/ solHA(vap)/ K kJ/mol kJ/mol _______________________________________________________________________________
ethane 288.15-323.15 +1.9 −6.7 hexafluoroethane 288.15-323.15 −8.2 −19.9 n-hexane 288.15-323.15 +13.0 −19.1 _______________________________________________________________________________
________________________________________________________________________
Polymer (B): poly[tetrafluoroethylene-co-perfluoro(methyl vinyl ether)] 2006BEL Characterization: 49.3 mol% perfluoro(methyl vinyl ether), Tg/K = 265.2, = 2.02 g/cm3, DuPont Performance Elastomers, L.L.C., Wilmington, DE ________________________________________________________________________
Solvent (A) T-range/ MHA/ solHA(vap)/ K kJ/mol kJ/mol _______________________________________________________________________________
Polymer (B) Solvent (A) Enthalpy T-range Ref. _______________________________________________________________________________
Poly(ethylene-co-ethyl acrylate) carbon dioxide solHA(vap) 423-473 K 2004ARE _______________________________________________________________________________
Poly(ethylene oxide-bpropylene oxide-bethylene oxide) water MH 298 K 2002THU water/surfactant H 2004DEL water/surfactant H 2004JAN _______________________________________________________________________________
Poly(ethylene oxide-cotetrahydrofuran) 2-propanol MH 303 K 1998STU tetrachloromethane MH 303 K 1998STU trichloromethane MH 303 K 1998STU _______________________________________________________________________________
Poly(N-isopropylacrylamide-co-acrylic acid) water H 2006WEN _______________________________________________________________________________
Poly(methyl methacrylateco-methacrylic acid) dibutyl phthalate MH 298 K 1991TAG didodecyl phthalate MH 298 K 1991TAG dioctyl phthalate MH 298 K 1991TAG dioctyl sebacate MH 298 K 1991TAG tetramethyl pyromellitate MH 298 K 1991TAG tricresyl phosphate MH 298 K 1991TAG _______________________________________________________________________________
Poly(styrene oxide-bethylene oxide) water/sodium dodecyl sulfate H 298 K 2005CAS _______________________________________________________________________________
________________________________________________________________________ 5.4. References 1991TAG Tager, A. A., Yushkova, S. M., Adamova, L. V., Kovylin, S. V., Berezov, L. V.,
Mozzhukhin, V. B., and Guzeev, V. V., Thermodynamics of interaction of methyl methacrylate-methacrylic acid copolymers with plasticizers and their mixtures (Russ.), Vysokomol. Soedin., Ser. A, 33, 357, 1991.
