ABSTRACT

Homogeneous chemical reactions occurring entirely in aqueous solution are rather rare in natural waters and wastewaters. Instead, most signišcant chemical and biochemical phenomena in water involve interactions between species in water and another phase. Some of these important interactions are illustrated in Figure 5.1. Several examples of phase interactions in water illustrated by the šgure are the following: production of solid biomass through the photosynthetic activity of algae occurs within a suspended algal cell and involves exchange of dissolved solids and gases between the surrounding water and the cell. Similar exchanges occur when bacteria degrade organic matter (often in the form of small particles) in water. Chemical reactions occur that produce solids or gases in water. Iron and many important trace-level elements are transported through aquatic systems as colloidal chemical compounds or are sorbed to solid particles. Pollutant hydrocarbons and some pesticides may be present on the water surface as an immiscible liquid šlm. Sediment can be washed physically into a body of water.