ABSTRACT

Fatty amines are cationic surfactants which are frequently employed as a collector in flotation for the purpose of creating a hydrophobic state at the surface of se­ lected particles. Amines are common collectors because in their cationic form they can adsorb at the negatively charged mineral surfaces. For example, a mix­ ture of primary and secondary amines is used to separate KC1 from NaCl and to float quartz from phosphate minerals. Extensive work by Gaudin on the mecha­ nism of flotation using cationic agents was done long ago [1]. Since these basic principles were identified, further investigations have explained the flotation mechanism in more detail [2]. It has been suggested that in some flotation proc­ esses where primary amines are used, a precipitate of the collector colloid forms or adsorbs at the mineral surface and accounts for flotation [3, 4].