ABSTRACT

The supramolecular model of the polymeric microreactor, developed on the basis of the broad experimental material, allowed formulation of the key structural-kinetic stage of the chain reaction (Section 3.9). In accordance with this model, all quasi-elementary stages of any chain reaction, proceeding in NCPM microreactor, are display highly heterogeneous physical origin. This drastically distinguishes the non-crystalline matrix of polymers from homogeneous heterophase and liquid-phase systems.