ABSTRACT

Obviously, the thermofluctuational state and mechanical properties of a polymeric melt differ from the physical state and properties of a glassy-like polymer. Meanwhile, kinetics of the chain BP degradation in polyethylene oxide (PEO) melt [1] reduplicates the reaction kinetics in the glassy-like polystyrene. Its analytical equation is qualitatively different from kinetic equations ofBP reaction with liquid dialkyl esters [2, 3].