ABSTRACT

When considering kinetic effects found under investigation of radical polymerization of acrylate-and methacrylate-anions in water solutions in dependence on pH medium the conclusion was made about important contribution of chain propagation reaction to AA and MAA polymerization process due to formation of ion pairs at macroradicals ends that was conformed by direct measuring of individual kinetic constants [ 1]. To obtain information about the influence of mentioned electrostatic interactions on copolymerization reaction direction the AA and MAA copolymerization in water and organic solutions with a number of comonomers was studied.