ABSTRACT

Mean Activity Coefficient at 25 °C m/mol kg-1 AgNO3 BaBr2 BaCl2 BaI2 CaBr2 CaCl2 CaI2

0.001 0.964 0.881 0.887 0.890 0.890 0.888 0.890 0.002 0.950 0.850 0.849 0.853 0.853 0.851 0.853 0.005 0.924 0.785 0.782 0.792 0.791 0.787 0.791 0.010 0.896 0.727 0.721 0.737 0.735 0.727 0.736 0.020 0.859 0.661 0.653 0.678 0.674 0.664 0.677 0.050 0.794 0.573 0.559 0.600 0.594 0.577 0.600 0.100 0.732 0.517 0.492 0.551 0.540 0.517 0.552 0.200 0.656 0.463 0.436 0.520 0.502 0.469 0.524 0.500 0.536 0.435 0.391 0.536 0.500 0.444 0.554 1.000 0.430 0.470 0.393 0.664 0.604 0.495 0.729 2.000 0.316 0.654 1.242 1.125 0.784 5.000 0.181 18.7 5.907

10.000 0.108 43.1 15.000 0.085

m/mol kg-1 Cd(NO2)2 Cd(NO3)2 CoBr2 CoCl2 CoI2 Co(NO3)2 CsBr 0.001 0.881 0.888 0.890 0.889 0.887 0.888 0.965 0.002 0.837 0.851 0.854 0.852 0.849 0.850 0.951 0.005 0.759 0.787 0.794 0.789 0.783 0.786 0.925 0.010 0.681 0.728 0.740 0.732 0.724 0.728 0.898 0.020 0.589 0.664 0.681 0.670 0.661 0.663 0.864 0.050 0.451 0.576 0.605 0.586 0.582 0.576 0.806 0.100 0.344 0.515 0.556 0.528 0.540 0.516 0.752 0.200 0.247 0.465 0.523 0.483 0.527 0.469 0.691 0.500 0.148 0.428 0.538 0.465 0.596 0.446 0.605 1.000 0.098 0.437 0.685 0.532 0.845 0.492 0.540 2.000 0.069 0.517 1.421 0.864 2.287 0.722 0.485 5.000 0.054 13.9 55.3 3.338 0.454

10.000 196

m/mol kg-1 CsCl CsF CsI CsNO3 CsOH Cs2SO4 CuBr2 0.001 0.965 0.965 0.965 0.964 0.966 0.885 0.889 0.002 0.951 0.952 0.951 0.951 0.953 0.845 0.853 0.005 0.925 0.929 0.925 0.924 0.930 0.775 0.791 0.010 0.898 0.905 0.898 0.897 0.906 0.709 0.735 0.020 0.864 0.876 0.863 0.860 0.878 0.634 0.674 0.050 0.805 0.830 0.804 0.796 0.836 0.526 0.594 0.100 0.751 0.792 0.749 0.733 0.802 0.444 0.541 0.200 0.691 0.755 0.688 0.655 0.772 0.369 0.504 0.500 0.607 0.721 0.601 0.529 0.755 0.285 0.503 1.000 0.546 0.726 0.534 0.421 0.782 0.233 0.591 2.000 0.496 0.803 0.470 0.859 5.000 0.474

10.000 0.508

2 42 32 2 4 0.001 0.887 0.890 0.888 0.888 0.966 0.965 0.966 0.002 0.849 0.854 0.851 0.850 0.953 0.952 0.953 0.005 0.783 0.795 0.787 0.785 0.930 0.929 0.929 0.010 0.722 0.741 0.729 0.725 0.907 0.905 0.906 0.020 0.654 0.685 0.664 0.659 0.879 0.876 0.878 0.050 0.561 0.613 0.577 0.570 0.837 0.832 0.836 0.100 0.495 0.572 0.516 0.509 0.806 0.797 0.803 0.200 0.441 0.553 0.466 0.462 0.783 0.768 0.776 0.500 0.401 0.617 0.431 0.443 0.790 0.759 0.769 1.000 0.405 0.892 0.456 0.500 0.872 0.811 0.826 2.000 0.453 2.445 0.615 0.782 1.167 1.009 1.055 5.000 0.601 2.083 3.800 2.380 3.100

10.000 33.4 10.4 30.8 15.000 323

m/mol kg-1 HF HI HNO3 H2SO4 KBr KCNS KCl 0.001 0.551 0.966 0.965 0.804 0.965 0.965 0.965 0.002 0.429 0.953 0.952 0.740 0.952 0.951 0.951 0.005 0.302 0.931 0.929 0.634 0.927 0.927 0.927 0.010 0.225 0.909 0.905 0.542 0.902 0.901 0.901 0.020 0.163 0.884 0.875 0.445 0.870 0.869 0.869 0.050 0.106 0.847 0.829 0.325 0.817 0.815 0.816 0.100 0.0766 0.823 0.792 0.251 0.771 0.768 0.768 0.200 0.0550 0.811 0.756 0.195 0.722 0.716 0.717 0.500 0.0352 0.845 0.725 0.146 0.658 0.647 0.649 1.000 0.0249 0.969 0.730 0.125 0.617 0.598 0.604 2.000 0.0175 1.363 0.788 0.119 0.593 0.556 0.573 5.000 0.0110 4.760 1.063 0.197 0.626 0.525 0.593

10.000 0.0085 49.100 1.644 0.527 15.000 0.0077 2.212 1.077 20.000 0.0075 2.607 1.701

m/mol kg-1 KClO3 K2CrO4 KF KH2PO4* K2HPO4** KI KNO3 0.001 0.965 0.886 0.965 0.964 0.886 0.965 0.964 0.002 0.951 0.847 0.952 0.950 0.847 0.952 0.950 0.005 0.926 0.779 0.927 0.924 0.779 0.927 0.924 0.010 0.899 0.715 0.902 0.896 0.715 0.902 0.896 0.020 0.865 0.643 0.870 0.859 0.643 0.871 0.860 0.050 0.805 0.539 0.818 0.793 0.538 0.820 0.797 0.100 0.749 0.460 0.773 0.730 0.457 0.776 0.735 0.200 0.681 0.385 0.726 0.652 0.379 0.731 0.662 0.500 0.569 0.296 0.670 0.529 0.283 0.676 0.546 1.000 0.239 0.645 0.422 0.646 0.444 2.000 0.199 0.658 0.638 0.332 5.000 0.871

10.000 1.715 15.000 3.120

m/mol kg-1 KOH K2SO4 LiBr LiCl LiClO4 LiI LiNO3 0.001 0.965 0.885 0.965 0.965 0.966 0.966 0.965 0.002 0.952 0.844 0.952 0.952 0.953 0.953 0.952 0.005 0.927 0.772 0.929 0.928 0.931 0.930 0.928 0.010 0.902 0.704 0.905 0.904 0.908 0.908 0.904 0.020 0.871 0.625 0.877 0.874 0.882 0.882 0.874 0.050 0.821 0.511 0.832 0.827 0.843 0.843 0.827 0.100 0.779 0.424 0.797 0.789 0.815 0.817 0.788 0.200 0.740 0.343 0.767 0.756 0.795 0.802 0.753 0.500 0.710 0.251 0.754 0.739 0.806 0.824 0.726 1.000 0.733 0.803 0.775 0.887 0.912 0.743 2.000 0.860 1.012 0.924 1.161 1.197 0.837 5.000 1.697 2.696 2.000 1.298

24 4 3 10.000 6.110 20.0 9.600 2.500 15.000 19.9 147 30.9 3.960 20.000 46.4 486 4.970

m/mol kg-1 LiOH Li2SO4 MgBr2 MgCl2 MgI2 MnBr2 MnCl2 0.001 0.964 0.887 0.889 0.889 0.889 0.889 0.888 0.002 0.950 0.847 0.852 0.852 0.853 0.853 0.850 0.005 0.923 0.780 0.790 0.790 0.791 0.791 0.786 0.010 0.895 0.716 0.733 0.734 0.736 0.735 0.727 0.020 0.858 0.645 0.672 0.672 0.677 0.674 0.662 0.050 0.794 0.544 0.593 0.590 0.602 0.595 0.574 0.100 0.735 0.469 0.543 0.535 0.556 0.543 0.513 0.200 0.668 0.400 0.512 0.493 0.535 0.508 0.464 0.500 0.579 0.325 0.540 0.485 0.594 0.519 0.437 1.000 0.522 0.284 0.715 0.577 0.858 0.650 0.477 2.000 0.484 0.270 1.590 1.065 2.326 1.224 0.661 5.000 0.493 36.1 14.40 109.8 6.697 1.539

m/mol kg-1 Mn(ClO4)2 NH4Cl NH4ClO4 (NH4)2HPO4** NH4NO3 NaBr NaBrO3 0.001 0.892 0.965 0.964 0.882 0.964 0.965 0.965 0.002 0.858 0.952 0.950 0.839 0.951 0.952 0.951 0.005 0.801 0.927 0.924 0.763 0.925 0.928 0.926 0.010 0.752 0.901 0.895 0.688 0.897 0.903 0.900 0.020 0.700 0.869 0.859 0.600 0.862 0.873 0.867 0.050 0.637 0.816 0.794 0.469 0.801 0.824 0.811 0.100 0.604 0.769 0.734 0.367 0.744 0.783 0.759 0.200 0.596 0.718 0.663 0.273 0.678 0.742 0.698 0.500 0.686 0.649 0.560 0.171 0.582 0.697 0.605 1.000 1.030 0.603 0.479 0.114 0.502 0.687 0.528 2.000 3.072 0.569 0.399 0.074 0.419 0.730 0.449 5.000 0.563 0.303 1.083

10.000 0.220 15.000 0.179 20.000 0.154

m/mol kg-1 Na2CO3 NaCl NaClO3 NaClO4 Na2CrO4 NaF Na2HPO4* 0.001 0.887 0.965 0.965 0.965 0.887 0.965 0.887 0.002 0.847 0.952 0.952 0.952 0.849 0.951 0.848 0.005 0.780 0.928 0.927 0.928 0.783 0.926 0.780 0.010 0.716 0.903 0.902 0.903 0.722 0.901 0.717 0.020 0.644 0.872 0.870 0.872 0.653 0.868 0.644 0.050 0.541 0.822 0.818 0.821 0.554 0.813 0.539 0.100 0.462 0.779 0.771 0.777 0.479 0.764 0.456 0.200 0.385 0.734 0.719 0.729 0.406 0.710 0.373 0.500 0.292 0.681 0.646 0.668 0.318 0.633 0.266 1.000 0.229 0.657 0.590 0.630 0.261 0.573 0.191 2.000 0.182 0.668 0.537 0.608 0.231 0.133 5.000 0.874 0.648

m/mol kg-1 NaI NaNO3 NaOH Na2SO3 Na2SO4 Na2WO4 NiBr2 0.001 0.965 0.965 0.965 0.887 0.886 0.886 0.889 0.002 0.952 0.951 0.952 0.847 0.846 0.846 0.853 0.005 0.928 0.926 0.927 0.779 0.777 0.777 0.791 0.010 0.904 0.900 0.902 0.716 0.712 0.712 0.735 0.020 0.874 0.866 0.870 0.644 0.637 0.638 0.675 0.050 0.827 0.810 0.819 0.540 0.529 0.534 0.596 0.100 0.789 0.759 0.775 0.462 0.446 0.457 0.546 0.200 0.753 0.701 0.731 0.386 0.366 0.388 0.514 0.500 0.722 0.617 0.685 0.296 0.268 0.320 0.535 1.000 0.734 0.550 0.674 0.237 0.204 0.291 0.692 2.000 0.823 0.480 0.714 0.196 0.155 0.291 1.476

10.000 4.011 0.329 3.258 15.000 9.796 20.000 19.410

m/mol kg-1 NiCl2 Ni(ClO4)2 Ni(NO3)2 Pb(ClO4)2 Pb(NO3)2 RbBr RbCl 0.001 0.889 0.891 0.889 0.889 0.882 0.965 0.965 0.002 0.852 0.855 0.851 0.851 0.840 0.951 0.951 0.005 0.789 0.797 0.787 0.787 0.764 0.926 0.926 0.010 0.732 0.745 0.730 0.729 0.690 0.900 0.900 0.020 0.669 0.690 0.666 0.666 0.604 0.866 0.867 0.050 0.584 0.621 0.581 0.580 0.476 0.811 0.811 0.100 0.527 0.582 0.524 0.522 0.379 0.760 0.761 0.200 0.482 0.567 0.481 0.476 0.291 0.705 0.707 0.500 0.465 0.639 0.467 0.458 0.195 0.630 0.633 1.000 0.538 0.946 0.528 0.516 0.136 0.578 0.583 2.000 0.915 2.812 0.797 0.799 0.535 0.546 5.000 4.785 4.043 0.514 0.544

10.000 33.8

m/mol kg-1 RbF RbI RbNO3 Rb2SO4 SrBr2 SrCl2 SrI2 0.001 0.965 0.965 0.964 0.886 0.889 0.888 0.890 0.002 0.952 0.951 0.950 0.845 0.852 0.850 0.854 0.005 0.927 0.926 0.924 0.776 0.790 0.785 0.793 0.010 0.902 0.900 0.896 0.710 0.734 0.725 0.740 0.020 0.871 0.866 0.859 0.635 0.673 0.659 0.681 0.050 0.821 0.810 0.795 0.526 0.591 0.569 0.606 0.100 0.780 0.759 0.733 0.443 0.535 0.506 0.557 0.200 0.739 0.703 0.657 0.365 0.492 0.455 0.526 0.500 0.701 0.627 0.536 0.274 0.476 0.421 0.542 1.000 0.697 0.574 0.430 0.217 0.545 0.451 0.686 2.000 0.724 0.532 0.320 0.921 0.650 5.000 0.517

m/mol kg-1 UO2Cl2 UO2(NO3)2 ZnBr2 ZnCl2 ZnI2 0.001 0.888 0.888 0.890 0.887 0.893 0.002 0.851 0.849 0.854 0.847 0.859 0.005 0.787 0.784 0.794 0.781 0.804 0.010 0.729 0.726 0.741 0.719 0.757 0.020 0.666 0.663 0.683 0.652 0.708 0.050 0.583 0.583 0.606 0.561 0.644 0.100 0.529 0.535 0.553 0.499 0.601 0.200 0.493 0.509 0.515 0.447 0.574 0.500 0.501 0.532 0.516 0.384 0.635 1.000 0.601 0.673 0.558 0.330 0.836 2.000 0.948 1.223 0.578 0.283 1.062 5.000 3.020 0.788 0.342 1.546

10.000 2.317 0.876 4.698 15.000 5.381 1.914 20.000 7.965 2.968