ABSTRACT
Polymer Mn/ Mw/ Solvent T/ A2 104/ Ref. g/mol g/mol K cm3mol/g2 _______________________________________________________________________________
Bovine serum albumin pH = 4.5 68000 water (0.15 M (NH4)2SO4) 298.15 −0.260 2009LUY pH = 4.5 68000 water (0.50 M (NH4)2SO4) 298.15 −0.036 2009LUY pH = 4.5 68000 water (1.00 M (NH4)2SO4) 298.15 −0.239 2009LUY pH = 4.5 68000 water (1.50 M (NH4)2SO4) 298.15 −0.765 2009LUY pH = 4.8 68000 water (0.15 M (NH4)2SO4) 298.15 −0.263 2009LUY pH = 4.8 68000 water (0.50 M (NH4)2SO4) 298.15 −0.199 2009LUY pH = 4.8 68000 water (1.00 M (NH4)2SO4) 298.15 −0.779 2009LUY pH = 4.8 68000 water (1.50 M (NH4)2SO4) 298.15 −1.159 2009LUY pH = 5.4 68000 water (0.15 M (NH4)2SO4) 298.15 −0.095 2009LUY pH = 5.4 68000 water (0.50 M (NH4)2SO4) 298.15 −0.107 2009LUY pH = 5.4 68000 water (1.00 M (NH4)2SO4) 298.15 −0.101 2009LUY pH = 5.4 68000 water (1.50 M (NH4)2SO4) 298.15 −0.347 2009LUY pH = 7.4 68000 water (0.15 M (NH4)2SO4) 298.15 −0.031 2009LUY pH = 7.4 68000 water (0.50 M (NH4)2SO4) 298.15 0.172 2009LUY pH = 7.4 68000 water (1.00 M (NH4)2SO4) 298.15 0.011 2009LUY pH = 7.4 68000 water (1.50 M (NH4)2SO4) 298.15 −0.027 2009LUY pH = 3.6 108879 water (0.1 M KCl) 298.15 0.26 2009PAR pH = 4.6 74541 water (0.1 M KCl) 298.15 1.13 2009PAR pH = 5.6 63420 water (0.1 M KCl) 298.15 0.92 2009PAR pH = 7.6 101010 water (0.1 M KCl) 298.15 1.71 2009PAR pH = 4.6 77927 water (1 M KCl) 298.15 0.63 2009PAR pH = 5.6 80316 water (1 M KCl) 298.15 1.26 2009PAR pH = 7.6 135544 water (1 M KCl) 298.15 2.29 2009PAR pH = 5.6 107814 water (3 M KCl) 298.15 1.39 2009PAR pH = 7.6 83623 water (3 M KCl) 298.15 1.35 2009PAR pH = 4.6 107559 water (0.01 M LiCl) 298.15 0.61 2009PAR pH = 5.6 93821 water (0.01 M LiCl) 298.15 0.80 2009PAR pH = 7.6 82510 water (0.01 M LiCl) 298.15 1.06 2009PAR pH = 4.6 94415 water (0.1 M LiCl) 298.15 0.64 2009PAR pH = 5.6 82470 water (0.1 M LiCl) 298.15 0.65 2009PAR pH = 7.6 117730 water (0.1 M LiCl) 298.15 1.15 2009PAR _______________________________________________________________________________
________________________________________________________________________
Polymer Mn/ Mw/ Solvent T/ A2 104/ Ref. g/mol g/mol K cm3mol/g2 _______________________________________________________________________________
Bovine serum albumin pH = 4.0 69100 water (buffered, 15 mM) 298.15 2.88 2011YAD pH = 5.0 67500 water (buffered, 15 mM) 298.15 −0.34 2011YAD pH = 6.0 73900 water (buffered, 15 mM) 298.15 1.31 2011YAD pH = 7.0 73300 water (buffered, 15 mM) 298.15 3.38 2011YAD _______________________________________________________________________________
Carboxymethylcellulose 680000 water (0.5 M NaCl) 298.15 5.2 2008VID _______________________________________________________________________________
Carboxymethylcellulose-g-poly(N,N-dihexylacrylamide) (1.1 mol% N,N-dihexylacrylamide) 730000 water (0.5 M NaCl) 298.15 2.4 2008VID (5.9 mol% N,N-dihexylacrylamide) 590000 water (0.5 M NaCl) 298.15 0.71 2008VID _______________________________________________________________________________
Carboxymethylstarch (from potato starch) (D.S. = 0.40) 1240000 water 298.15 8.26 2009STO (D.S. = 0.40) 2320000 water (0.01 M NaCl) 298.15 2.010 2009STO (D.S. = 0.40) 1710000 water (0.05 M NaCl) 298.15 0.298 2009STO (D.S. = 0.40) 1920000 water (0.10 M NaCl) 298.15 0.862 2009STO (D.S. = 0.40) 2170000 water (0.50 M NaCl) 298.15 0.455 2009STO (D.S. = 0.81) 838000 water 298.15 11.10 2009STO (D.S. = 0.81) 1160000 water (0.01 M NaCl) 298.15 3.33 2009STO (D.S. = 0.81) 895000 water (0.05 M NaCl) 298.15 1.84 2009STO (D.S. = 0.81) 857000 water (0.10 M NaCl) 298.15 1.59 2009STO (D.S. = 0.81) 972000 water (0.50 M NaCl) 298.15 1.04 2009STO (D.S. = 0.90) 8090000 water 298.15 1.81 2009STO (D.S. = 0.90) 18200000 water (0.01 M NaCl) 298.15 0.374 2009STO (D.S. = 0.90) 20900000 water (0.05 M NaCl) 298.15 0.123 2009STO (D.S. = 0.90) 20800000 water (0.10 M NaCl) 298.15 0.084 2009STO (D.S. = 0.90) 20500000 water (0.50 M NaCl) 298.15 0.041 2009STO
Carboxymethylstarch (from corn starch) (D.S. = 0.50) 3520000 water 298.15 1.93 2009STO (D.S. = 0.50) 5550000 water (0.01 M NaCl) 298.15 0.064 2009STO (D.S. = 0.50) 4880000 water (0.05 M NaCl) 298.15 0.007 2009STO (D.S. = 0.50) 4990000 water (0.10 M NaCl) 298.15 −0.005 2009STO (D.S. = 0.50) 4820000 water (0.50 M NaCl) 298.15 −0.030 2009STO (D.S. = 0.70) 8630000 water 298.15 0.085 2009STO (D.S. = 0.70) 13500000 water (0.01 M NaCl) 298.15 0.048 2009STO (D.S. = 0.70) 13300000 water (0.05 M NaCl) 298.15 0.005 2009STO (D.S. = 0.70) 19300000 water (0.10 M NaCl) 298.15 0.016 2009STO (D.S. = 0.70) 15200000 water (0.50 M NaCl) 298.15 0.011 2009STO (D.S. = 1.10) 4570000 water 298.15 1.51 2009STO (D.S. = 1.10) 5860000 water (0.01 M NaCl) 298.15 0.073 2009STO _______________________________________________________________________________
2 ________________________________________________________________________
Polymer Mn/ Mw/ Solvent T/ A2 104/ Ref. g/mol g/mol K cm3mol/g2 _______________________________________________________________________________
Carboxymethylstarch (from corn starch) (D.S. = 1.10) 6320000 water (0.05 M NaCl) 298.15 0.032 2009STO (D.S. = 1.10) 6380000 water (0.10 M NaCl) 298.15 0.029 2009STO (D.S. = 1.10) 6290000 water (0.50 M NaCl) 298.15 0.011 2009STO _______________________________________________________________________________
Cellulose 27000 water (4.6 wt% LiOH/ 15 wt% urea) 298.15 33.1 2006CAI 65000 water (4.6 wt% LiOH/ 15 wt% urea) 298.15 33.3 2006CAI 68000 water (4.6 wt% LiOH/ 15 wt% urea) 298.15 31.0 2006CAI 83000 water (4.6 wt% LiOH/ 15 wt% urea) 298.15 44.1 2006CAI 84000 water (4.6 wt% LiOH/ 15 wt% urea) 298.15 39.4 2006CAI 86000 water (4.6 wt% LiOH/ 15 wt% urea) 298.15 33.3 2006CAI 92000 water (4.6 wt% LiOH/ 15 wt% urea) 298.15 37.7 2006CAI 120000 water (4.6 wt% LiOH/ 15 wt% urea) 298.15 14.9 2006CAI 148000 water (4.6 wt% LiOH/ 15 wt% urea) 298.15 20.4 2006CAI 195000 water (4.6 wt% LiOH/ 15 wt% urea) 298.15 13.5 2006CAI 412000 water (4.6 wt% LiOH/ 15 wt% urea) 298.15 15.8 2006CAI _______________________________________________________________________________
Dextran 40600 water 298.15 5.7 2005ROT 161000 water 298.15 2.59 2005SUG 595000 water 298.15 2.1 2005ROT 347000 water 302.05 3.0 2007SCH _______________________________________________________________________________
Hydroxyethylcellulose (derivative with triethylammonium chloride) 260000 water (phosphate buffered saline, pH = 7.4) 308.15 9.3 2009GAO 420000 water (phosphate buffered saline, pH = 7.4) 308.15 8.9 2009GAO 1030000 water (phosphate buffered saline, pH = 7.4) 308.15 7.9 2009GAO _______________________________________________________________________________
________________________________________________________________________
Polymer Mn/ Mw/ Solvent T/ A2 104/ Ref. g/mol g/mol K cm3mol/g2 _______________________________________________________________________________
Hydroxypropylguar (D.S.) = 1.2 5000000 water 313.15 −1.0 2010RIS _______________________________________________________________________________
Hydroxypropylstarch 9700000 water 293.15 0.21 2004VOR 43600000 water 293.15 0.11 2004VOR _______________________________________________________________________________
Inulin 1030000 water 298.15 2.22 2009DAN _______________________________________________________________________________
β-Lactoglobulin 36500 water 302.05 −2.2 2007SCH _______________________________________________________________________________
Maltodextrin 2000 10000 water 298.15 2.13 2005NIN _______________________________________________________________________________
Maltotriose 504 water 298.15 5.72 2005NIN _______________________________________________________________________________
Methylguar (D.S. = 0.3) 2600000 water 313.15 1.4 2010RIS _______________________________________________________________________________
Methyl(hydroxypropyl)guar (D.S. = 0.4/1.2) 1000000 water 313.15 1.5 2010RIS _______________________________________________________________________________
Poly(acrylamide) 74800 water 298.15 6.30 2004ALB 463000 water 298.15 4.80 2004ALB 1829000 water 298.15 4.46 2004ALB _______________________________________________________________________________
Poly(acrylic acid) 94000 water (0.1 M HCl) 333.15 3.0 2010LIT 94000 water (0.2 M HCl) 333.15 5.8 2010LIT 161000 water (0.1 M HCl) 313.15 1.8 2009LIT _______________________________________________________________________________
2 ________________________________________________________________________
Polymer Mn/ Mw/ Solvent T/ A2 104/ Ref. g/mol g/mol K cm3mol/g2 _______________________________________________________________________________
Poly(N-decylacrylamide-b-N,N-diethylacrylamide) (micellar) 815000 water 293.15 8.6 2008ZHO _______________________________________________________________________________
Poly(N,N-diallyl-N,N-dimethylammonium chloride) 400000 water (0.1 M HCl) 293.15 15 2010LIT 400000 water (0.1 M HCl) 318.15 18 2010LIT 415000 water (0.1 M HCl) 313.15 17.7 2009LIT _______________________________________________________________________________
Poly(N,N-diallyl-N-methylammonium acetate) 22000 water (1 M NaCl) 298.15 2.8 2011LEZ 60000 water (1 M NaCl) 298.15 3.2 2011LEZ 104000 water (1 M NaCl) 298.15 3.5 2011LEZ 112000 water (1 M NaCl) 298.15 2.5 2011LEZ 178000 water (1 M NaCl) 298.15 2.1 2011LEZ _______________________________________________________________________________
Poly(N,N-diethylacrylamide) 17000000 water 300.15 0.2 2008ZHO 17000000 water 301.15 0.1 2008ZHO 17000000 water 301.65 0.0 2008ZHO _______________________________________________________________________________
Poly(N,N-dimethylacrylamide) 15600 16700 water 298.15 8.0 2006LAM 47300 53900 water 298.15 7.8 2006LAM _______________________________________________________________________________
Poly(N,N-dimethylacrylamide-b-N-isopropylacrylamide-b-N,N-dimethylacrylamide) (72 mol% NIPAM) 41300 42500 water 323.15 3.78 2006CON (78 mol% NIPAM) 53000 60400 water 323.15 2.58 2006CON _______________________________________________________________________________
Poly[2-(2-ethoxy)ethoxyethyl vinyl ether] 21900 water 298.15 6.6 2005MAT 21900 water 308.15 2.4 2005MAT 21900 water 311.15 0.7 2005MAT 21900 water 313.15 −1.1 2005MAT 30400 water 298.15 6.6 2005MAT 30400 water 308.15 2.7 2005MAT 30400 water 311.15 0.5 2005MAT 30400 water 313.15 −0.6 2005MAT _______________________________________________________________________________
________________________________________________________________________
Polymer Mn/ Mw/ Solvent T/ A2 104/ Ref. g/mol g/mol K cm3mol/g2 _______________________________________________________________________________
Poly(ethoxyethyl glycidyl ether) 103000 water 298.15 5.59 2007RA1 199000 water 298.15 6.15 2007RA1 446000 water 298.15 5.35 2007RA1 1093000 water 298.15 4.74 2007RA1 1806000 water 298.15 4.31 2007RA1 2330000 water 298.15 4.40 2007RA1 _______________________________________________________________________________
Poly(ethylene glycol) 1290 1730 water 298.15 24.0 2006OZD 1290 1730 water 303.15 16.9 2006OZD 1290 1730 water 308.15 14.8 2006OZD 1290 1730 water 313.15 11.6 2006OZD 3540 4600 water 298.15 28.9 2006OZD 3540 4600 water 303.15 19.5 2006OZD 3540 4600 water 308.15 16.9 2006OZD 3540 4600 water 313.15 13.0 2006OZD 7020 8000 water 298.15 33.2 2006OZD 7020 8000 water 303.15 21.8 2006OZD 7020 8000 water 308.15 18.4 2006OZD 7020 8000 water 313.15 13.9 2006OZD 5370 10640 water 298.15 36.2 2006OZD 5370 10640 water 303.15 23.4 2006OZD 5370 10640 water 308.15 20.0 2006OZD 5370 10640 water 313.15 14.9 2006OZD _______________________________________________________________________________
Poly(ethylene oxide) 625000 water 298.15 6.57 2006KHA 896000 water 298.15 0.30 2006KHA 1038000 water 298.15 9.65 2006KHA _______________________________________________________________________________
Poly(ethylene oxide-b-(R)-3-hydroxybutyrate-b-ethylene oxide) (81.8 wt% EO) 2000-810-2000 water 298.15 −3.2 2006LIX (92.4 wt% eEO) 5000-780-5000 water 298.15 0.27 2006LIX _______________________________________________________________________________
Poly(glycidol-b-propylene oxide-b-glycidol) (20 wt% propylene oxide) water 298.15 0.384 2007RA2 (20 wt% propylene oxide) water 313.15 0.226 2007RA2 (20 wt% propylene oxide) water 323.15 0.573 2007RA2 (20 wt% propylene oxide) water 333.15 0.076 2007RA2 _______________________________________________________________________________
2 ________________________________________________________________________
Polymer Mn/ Mw/ Solvent T/ A2 104/ Ref. g/mol g/mol K cm3mol/g2 _______________________________________________________________________________
Poly(glycidol-b-propylene oxide-b-glycidol) (30 wt% propylene oxide) water 298.15 0.074 2007RA2 (30 wt% propylene oxide) water 313.15 0.454 2007RA2 (30 wt% propylene oxide) water 323.15 0.266 2007RA2 (30 wt% propylene oxide) water 333.15 0.283 2007RA2 (70 wt% propylene oxide) water 298.15 −0.194 2007RA2 (70 wt% propylene oxide) water 313.15 −0.482 2007RA2 (70 wt% propylene oxide) water 323.15 −0.873 2007RA2 (70 wt% propylene oxide) water 333.15 −0.499 2007RA2 _______________________________________________________________________________
Poly(N-isopropylacrylamide) 3900000 water 295.35 1.4 2003STI 3900000 water 298.95 1.2 2003STI 3900000 water 303.45 0.50 2003STI 3900000 water 306.75 0.18 2003STI 3900000 water 308.95 −0.009 2003STI 3900000 water 309.65 −0.01 2003STI _______________________________________________________________________________
Poly(N-isopropylacrylamide) stereoblock polymer (isotactic-atactic-isotactic) i2-a28-i2 36700 water 293.15 9.7 2008NUO i2-a40-i2 47100 water 293.15 2.2 2008NUO _______________________________________________________________________________
Poly(N-isopropylacrylamide-b-N,N-dimethylacrylamide) (33 wt% NIPAM) 35300 39500 water 305.15 0.2 2006LAM (42 mol% NIPAM) 17900 19700 water 323.15 3.03 2006CON (64 mol% NIPAM) 29600 34000 water 323.15 1.11 2006CON (71 mol% NIPAM) 38600 43200 water 323.15 1.14 2006CON (82 mol% NIPAM) 61900 74900 water 323.15 1.10 2006CON _______________________________________________________________________________
Poly(N-isopropylacrylamide-b-L-glutamic acid) (NIPAM55-b-LGA35) 3370000 water (pH = 3) 298.15 −2.05 2008DEN _______________________________________________________________________________
Poly{N-isopropylacrylamide-co-3-[N-(3-methacrylamidopropyl)-N,N-dimethylammonio] propane sulfate} (2 mol% 3-[MAPDMA]PS) 300000 water 298.15 −11 2005NED (3 mol% 3-[MAPDMA]PS) 240000 water 298.15 −14 2005NED (5 mol% 3-[MAPDMA]PS) 250000 water 298.15 −11 2005NED (10 mol% 3-[MAPDMA]PS) 380000 water 298.15 −18 2005NED _______________________________________________________________________________
________________________________________________________________________
Polymer Mn/ Mw/ Solvent T/ A2 104/ Ref. g/mol g/mol K cm3mol/g2 _______________________________________________________________________________
Poly(sodium acrylate) 73000 water (0.1 M NaCl) 298.15 24.1 2003SCH 90000 water (0.1 M NaCl) 298.15 23.5 2003SCH 113000 water (0.1 M NaCl) 298.15 15.6 2003SCH 174000 water (0.1 M NaCl) 298.15 19.1 2003SCH 491000 water (0.1 M NaCl) 298.15 14.3 2003SCH 575000 water (0.1 M NaCl) 298.15 8.70 2003SCH 950000 water (0.1 M NaCl) 298.15 11.2 2003SCH 2390000 water (0.1 M NaCl) 298.15 6.39 2003SCH 3300000 water (0.1 M NaCl) 298.15 6.56 2003SCH 171000 water (0.1 M NaCl) 298.15 1.24 2003SCH 473000 water (0.1 M NaCl) 298.15 0.77 2003SCH 700000 water (0.1 M NaCl) 298.15 0.03 2003SCH 907000 water (0.1 M NaCl) 298.15 0.92 2003SCH 2610000 water (0.1 M NaCl) 298.15 0.56 2003SCH 3150000 water (0.1 M NaCl) 298.15 0.053 2003SCH _______________________________________________________________________________
Poly(styrene-b-ethylene oxide) (PS:PEO = 1:2) 689000 water 298.15 0.42 2010AHM _______________________________________________________________________________
Poly(vinyl alcohol) 85500 water 303.15 1.8 2000HON _______________________________________________________________________________
Poly(N-vinylcaprolactam-co-1-vinylimidazole) (26.0 mol% 1-vinylimidazole) 254000 water 293.15 −4.0 2006LOZ (26.0 mol% 1-vinylimidazole) 254000 water 323.15 −12.0 2006LOZ (27.0 mol% 1-vinylimidazole) 30000 water 293.15 −18.0 2006LOZ (27.0 mol% 1-vinylimidazole) 30000 water 323.15 9.0 2006LOZ (38.0 mol% 1-vinylimidazole) 66000 water 293.15 9.0 2006LOZ (38.0 mol% 1-vinylimidazole) 66000 water 323.15 5.0 2006LOZ (38.5 mol% 1-vinylimidazole) 28000 water 293.15 19.0 2006LOZ (38.5 mol% 1-vinylimidazole) 28000 water 323.15 14.0 2006LOZ _______________________________________________________________________________
Poly(1-vinylimidazole) 35000 water (0.2 M NaCl, pH =3 ) 298.15 34.6 2009MAS 193000 water (0.2 M NaCl, pH =3 ) 298.15 29.2 2009MAS _______________________________________________________________________________
2 ________________________________________________________________________
Polymer Mn/ Mw/ Solvent T/ A2 104/ Ref. g/mol g/mol K cm3mol/g2 _______________________________________________________________________________
Poly(1-vinyl-2-pyrrolidinone) 360000 water 298.15 5.02 2008KAR 360000 water 323.15 6.78 2008KAR _______________________________________________________________________________
Sodium hyaluronate 453000 water (0.1 M sodium phosphate buffer) 298.15 27.8 2010POD 453000 water (0.05 M Na2SO4) 298.15 34.5 2010POD _______________________________________________________________________________
________________________________________________________________________ 7.2. References 2000HON Hong, P.-D. and Huang, H.-T., Effect of co-solvent complex on preferential
adsorption phenomenon in polyvinyl alcohol ternary solutions, Polymer, 41, 6195, 2000.
