ABSTRACT

Up to this point, our study of quantum mechanics has concerned itself with the behaviour of particles that inhabit a Galilean spacetime. For many purposes, in atomic, molecular and condensed matter physics, this theory is quite adequate. We saw in earlier chapters, however, that our actual spacetime has a structure which is much closer to that of the Minkowski spacetime of special relativity and that more general structures must be considered when gravitational phenomena are signicant. From a purely theoretical point of view, it is therefore important to formulate quantum theory in a way which is consistent with these more general spacetimes. The benets of constructing a relativistic quantum theory actually go far beyond the aesthetic satisfaction of making our geometrical and quantum-mechanical reasoning compatible. For one thing, we shall discover that the relativistic theory provides a deeper understanding of spin and the distinction between fermions and bosons, which in the non-relativistic theory appear simply as facts of life that we must strive to accommodate. Also, of course, there are many situations in which relativistic eects become observable, for which non-relativistic theory provides no explanation. The most obvious are high-energy scattering experiments, in which particles acquire kinetic energies comparable with or greater than their rest energies mc2, and the correct 4-momentum (3.33) must be used. There are, however, more subtle eects, such as the spin-orbit coupling that is essential for interpreting atomic spectra, which are also of relativistic origin.