ABSTRACT
In 1897, Thomson demonstrated that cathode rays (observed to be emitted from the cathodes of vacuum tubes) were in fact charged particles which he called electrons. Thomson proposed that the atom consisted of a positively charged sphere in which were embedded negatively charged electrons. Rutherford subsequently found in 1911 that the electrons orbited at some distance from a central positively charged nucleus. Rutherford proposed that electrostatic attraction between the nucleus and the electron was balanced by the centrifugal force arising from the orbital motion. However, if this were the case, then the electrons (being accelerated inwards towards the center of rotation) would continuously radiate all their energy as electromagnetic waves and very quickly fall into the nucleus. In 1913, Bohr postulated two important additions to Rutherford’s theory of atomic structure: 1. Electrons can orbit the nucleus in what
are called stationary states in which no emission of radiation occurs and in which the angular momentum L is constrained to have values:
2. Electrons can make transitions from one state to another accompanied by the emission or absorption of a single photon of energy E = hf thus leading to absorption and emission spectra.
