ABSTRACT

Hydrogen usually forms compounds with other atoms that are more electronegative. It can be of as acting as a reductant.Inthatcase,itsoxidationnumberis+ 1 :

hydrogen atom

(oxidation number 0)

H+ + e­ hydrogen ion

H : 0: H

COOI 2e-

CH2 I

(5 . 1 )

CH2 I

The two carbons change their oxidation number from - 1 to - 2. The standard redox potential for the reaction is around o V. A more negative redox potential (around -0. 3 V) is found for the reduction of a ketone to an alcohoL In this case the carbon changes its oxidation state from +2 to O.