ABSTRACT

I. Introduction ........................................................................................................................ 1394 II.One-Electron Activation of Organometallic Complexes in Transition Metal-Catalyzed

Electrosyntheses ................................................................................................................. 1395 A.Electroreductive Carboxylation of Aryl Halides Catalyzed by Nickel ....................... 1395 B. Electroreductive Carboxylation of α-Methylbenzyl Chlorides Catalyzed by Nickel .... 1397 C. Electroreductive Homocoupling of Aryl/Vinyl Halides Catalyzed by Nickel ........... 1398

1.Electroreductive Homocoupling of Aryl Halides Catalyzed by Nickel ............... 1398 2.Electroreductive Homocoupling of Vinyl Halides Catalyzed by Nickel ............. 1400

D.Electroreductive Polymerization of Organic Dihalides Catalyzed by Nickel ............ 1401 E.Electroreductive Heterocoupling of Two Organic Halides Catalyzed by Nickel ....... 1402 F. Electroreductive Heterocoupling of Aryl Halides with Vinylic/Allylic Acetates

or Aryl Halides Catalyzed by Cobalt.......................................................................... 1404 III. Two-Electron Activation of Organometallic Complexes in Transition Metal-Catalyzed

Electrosyntheses ................................................................................................................. 1406 A. Electroreductive Carboxylation of Aryl Halides/TriŽates Catalyzed by Palladium .......1406